Nuclear Double Resonance between Statistical Spin Polarizations
نویسندگان
چکیده
منابع مشابه
Nuclear double resonance between statistical spin polarizations.
We demonstrate nuclear double resonance for nanometer-scale volumes of spins where random fluctuations rather than Boltzmann polarization dominate. When the Hartmann-Hahn condition is met in a cross-polarization experiment, flip-flops occur between two species of spins and their fluctuations become coupled. We use magnetic resonance force microscopy to measure this effect between 1H and 13C spi...
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group. The spectra, as shown in Figure 2 , can be semiquantitatively reproduced using the LAOCOON computer program with reduced values for the carbon-proton coupling constant^.^ These calculations are approximate because they do not include the asymmetry introduced by the decoupling field or any relaxation effects. We have performed additional experiments which show that it is not necessary for...
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ژورنال
عنوان ژورنال: Physical Review Letters
سال: 2009
ISSN: 0031-9007,1079-7114
DOI: 10.1103/physrevlett.102.087604